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Title: Advanced Questions ON GENERAL ORGANIC CHEMISTRY
Description: This PDF files contains "Advanced Problems on GENERAL ORGANIC CHEMISTRY" which are very crucial to solve to understand the core concepts of this Topic and the intial phase of Organic Chemistry. These questions are at par with the level of questions asked in one of the world's toughest Exam i.e "JEE ADVANCED " in India.

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GENERAL ORGANIC CHEMISTRY

CAPS-6

CHEMISTRY

GENERAL ORGANIC

TARGET : JEE- Advanced

CHEMISTRY

SINGLE CHOICE QUESTIONS
1
...


Correct order of basic strength of this compound is
(A) d > b > c > a
3
...


(D) a > d > c > b

(B) a > b > c > d

(C) c > d > a > b

(D) b > a > d > c

Compare C–H bond energy
...


(C) c > a > b > d

Compare rotational energy barrier for the indicated bond
...


(B) c > b > a > d

(B)

(C)

(D)

The correct order at resonance energy in following
...
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Page # 36

GENERAL ORGANIC CHEMISTRY

7
...


Which molecule has least rotational energy barrier for bond indicated by 
...


Statement-2 : + I effect of Me2CH– is more than that of Me–
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for
statement-1
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
statement-1
...

(D) Statement-1 is false, statement-2 is true
...


Which of the alkene will have maximum Heat of hydrogenation

(A)

(B)

(C)

(D)

MULTIPLE CHOICE QUESTIONS
10
...


The tautomeric pairs are
(A) Me2C = NOH and Me2CH–N=O

(B) CH2=CH–NHCH3 and CH3–CH=N–CH3

(C)

(D)

and

and

Which of the given statement is/are not correct?
(A)

is less acidic than CH2 = CH – CH2 – CH = CH2
...
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Page # 37

GENERAL ORGANIC CHEMISTRY

12
...


Which of the following pairs has 1st having more resonance energy than 2nd
...

(A)

is more basic than

(B)

is more acidic than

(C) HC  CH is more acidic than NH3
O

(D)
14
...

(A)

are positional isomers

(B)

are functional isomers

(C)

have identical resonance energy
...


is more stable than Me – C – O–

have identical resonance energy
...


(A)

(B)

(C)

(D)

OFFICE ADDRESS : PLOT NUMBER 35, GOPALPURA BYPASS ROAD, NEAR RIDDHI SIDDHI CIRCLE,
10-B SCHEME, TRIVENI NAGAR, G OPAL PURA MODE, JAIPUR, RAJASTHAN 302020
Mob
...
competishun
...


Select the correct order among the following:
(A) Order of heat of hydrogenation
(B) Order of heat of combustion

(C) Order of resonance energy

(D) Order of basic strength
Paragraph for question nos
...


The correct order of acidic strength of underhed H is
(A) III > I > II > IV

18
...


(B) I > II > IV > III
(B) 7

(C) 9

(D) 10

The correct order of bond energy of the marked C – H bond homolysis is:
(A) a > b > c > d

(B) d > c > b > a

(C) c > b > d > a

(D) d > c > a > b

INTEGER ANSWER TYPE
20
...
8888000021, 7410900901, 7410900906, 7410900907, 7410900908
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Page # 39

GENERAL ORGANIC CHEMISTRY

21
...

(a) Me – C C–H + NaOH  Me – C C–Na + H2O

O

(b) Ph  OH  NaHCO3  Ph O Na  H2 CO3
 
O

(c) Et  COOH  NaNH2  EtCO O Na  NH3
OH
+ 2 KOH 

(d)

OH

22
...

(b) How many grams of CO2 is released when 84 gm of sodium bicarbonate is treated with
excess of acetic acid
...

For example: if Answer of (a) is 12 and (b) is 13 you will fill 1213 in OMR sheet
...


How many neutral (Benzoid) resonating structures are possible for
...


Find out total no
...


Find out total no
...
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Page # 40

GENERAL ORGANIC CHEMISTRY

26
...

Column I

Column II

(A)

(P) Group attached to the benzene ring is +M effect showing group

(B)

(Q)Group attached to the benzene ring is –M effect showing group

(C)

(R) Group attached to the benzene ring is + H showing group
...


Column I

Column II

(Compounds)

(Magnitude of heat of hydrogenation)

(A)

(P) 52
...
9 Kcal / mole

(C)

(R) 26
...
7 Kcal / mole

Answer Key CAPS-6
1
...


(B)

3
...


(B)

5
...


(C)

7
...


(D)

9
...


(AB)

11
...


(BD)

13
...


(BC)

15
...


(BCD)

17
...


(C)

19
...


(10)

21
...


(5444)

23
...


(7)

25
...


(A) R, T (B) P, S, T (C) Q, S, T (D) P,Q,R,S, T

27
...
8888000021, 7410900901, 7410900906, 7410900907, 7410900908
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...
com

Page # 41


Title: Advanced Questions ON GENERAL ORGANIC CHEMISTRY
Description: This PDF files contains "Advanced Problems on GENERAL ORGANIC CHEMISTRY" which are very crucial to solve to understand the core concepts of this Topic and the intial phase of Organic Chemistry. These questions are at par with the level of questions asked in one of the world's toughest Exam i.e "JEE ADVANCED " in India.