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Title: A Level Chemistry - Carbon fuels
Description: AS Chemistry notes on carbon fuels.

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Kate Nicholls
Chemistry – Mrs MacAdie

10/1/11

DF8 – comparing pollutants from petrol and diesel cars
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034
0
0
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317
0
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184

No clear environmental advantage in buying a modern diesel or petrol car
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Diesel oxidation catalyst uses excess O2 in the exhaust gas stream to oxidise CO to CO2 and
hydrocarbons to H2O and CO2
Good at reducing/virtually eliminating the smell of diesel & helps to reduce soot
...

Catalytic converters are unable to remove tiny carbon particles but these can be partially
removed by a DPF (diesel particulate filter)
...

Aromatic hydrocarbons make up 40% of petrol
...

Benzene is worst – strictly controlled
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Butane & aromatic hydrocarbons – high octane components of petrol – if they are removed
then something must be added to replace them
...

US – attempts to produce reformulated gasoline’s that have:
o Low volatility – reducing the concentration of hydrocarbons in the atmosphere ;
o Reduced concentrations of benzene
o Added oxygenates (improve burning and so reduce the concentration of pollutants –
CO)
All this has to be achieved without reducing efficiency
...


Kate Nicholls
Chemistry – Mrs MacAdie

o

o

o

10/1/11

 Autogas has higher octane number & produces 20% less CO2 per mile than petrol/
 Releases less CO – higher ratio C:H
 Fewer un-burnt hydrocarbons & NOx than petrol
 Road tax is less for user
 LPG filling stations still relatively rare
 Liquid Natural Gas (LNG) – mainly methane and comes from oil and natural gas fields
 Methane cannot be liquid by pressure alone, it has to be cooled below -160oC
...

Biodiesel
 Ordinary engines can use
 Fuel made from vegetable oil or animal fat
 Made through transesterification
 Converts veg oil/animal fat into esterified oil – can be used as diesel or mixed with
diesel
...
must
all be exploited as much as possible
...



Title: A Level Chemistry - Carbon fuels
Description: AS Chemistry notes on carbon fuels.