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Title: Functional Groups
Description: This is a very helpful summary on the functional groups that can be added to a hydrocarbon, such as: Hydroxyl groups Amino groups Carboxylic acid groups

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Module: BIOM – 1007

Lecturer: Dr Weldon

Date: 21/11/16

Functional Groups
Functional
Group
Hydroxyl

Ether

Formula

Class of
Compound
Alcohols

Alkoxy’s

Naming

Replacing -yl
with -oxy on
shortest alkyl

Methoxymethane Short – Yes
Butoxybutane
Long – No
Ethoxyethane

Formyl

Aldehydes

Carboxyl

Amino

Short – Yes
Long – No

Propanol
Ethanol
Butanol

Ketones

Ester

Solubility

-ol

Using name of
parent alkane
of longest alkyl
-one

Carbonyl

Example

Butanone
Propanone
Methanone

Short – Yes
Long – No

-al

Methanal
Butanal
Propanal
Formaldehyde

Short – Yes
Long – No

Carboxylic
Acid’s

-oic acid

Ethanoic acid
Butanoid acid
Hexanoic acid

Short – Yes
Long – No

Esters

-yl -oate

Ethyl acetate
Methyl acetate

Short – Yes
Long – No

Primary amine

-amine

Propanamine
Methamine
1-Methyl
propanameine

Short – Yes
Long – No

(HIGH BP)
Secondary
amine
(MOD BP)
Tertiary amine
(LOW BP)

Functional
Group
Amide

Formula

Halo

R-X

Thiols

Class of
Compound
Amides

Haloalkanes
(X = F, Br, Cl or I)
Sulfhydryl’s

Naming

Example

Solubility

Replacing oic acid with amide

Ethanamide

Short – Yes
Long – No

‘Shortened
halogen
name’-thiol

Chloromethane
Fluorobutane

Very slightly

Butanethiol
Ethanethiol

Very slightly if
at all


Title: Functional Groups
Description: This is a very helpful summary on the functional groups that can be added to a hydrocarbon, such as: Hydroxyl groups Amino groups Carboxylic acid groups