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Choice Based Credit System
(CBCS)
B
...
with Industrial
Chemistry
University of Delhi
UNDERGRADUATE PROGRAMME
(Courses effective from Academic Year 20xx-xx)
SYLLABUS OF COURSES TO BE OFFERED: Core Courses, Elective Courses
& Ability Enhancement Courses
Page 1 of 109
Introduction:
The Choice based credit system (CBCS) offers flexibility of program structure while ensuring
that students gets a strong foundation in the subject and gains in-depth knowledge of all aspects
of the field
...
Duration of Program:
The B
...
Applied Physical Sciences with Industrial Chemistry program will be of three year
duration
...
Thus there will be a total of six semesters
...
Design of Program:
The teaching learning process will involve theory classes (Periods) of on hour duration and
practical classes of four hour duration
...
The assessment broadly will comprises of Internal
Assessment (Continuous Evaluation) and End Semester Examination
...
The
internal assessment will be through MCQ, test, assignment, oral presentation, worksheets and
short projects
...
Structure of Program:
The program will consist of six credit courses and four credit courses
...
Four credit courses will
be comprises of theory classes (two credits) and practical (two credits)
...
Each practical batch will be of fifteen students
...
The program includes Core Courses (CC) and elective courses
...
There are two kinds of elective courses: Discipline-Specific Elective (DSE),
and Skill Enhancement Course (SEC)
...
To acquire a degree in B
...
Applied Physical Sciences with Industrial Chemistry program a
student must study twelve core courses, six Discipline Specific Elective, four Skill Enhancement
courses
...
The Skill
Enhancement Course are four-credit courses while the Ability Enhancement courses are four
credit courses
...
Sc
...
The program offers Discipline-Specific Elective (DSEs) Chemistry, Industrial Chemistry and
Mathophysics, of which the students must choose one in each of the Semesters V and VI
...
A particular
option of DSE course will be offered in Semesters V and VI semesters only if the minimum
number of students opting for that course is 10
...
The number of students who will be allowed to opt for project work will vary
from college to college depending upon the infrastructural facilities and may vary each year
...
Project work will involve experimental work and the
student will have to do this in the time after their regular theory and practical classes
...
In this regard guidelines provided by University of Delhi for executing and evaluation of project
work will be final
...
The students will undertake four Skill Enhancement (SE) Course for four credits in Chemistry/
Industrial Chemistry each in semester III and IV, which they can choose from the list of SE
courses offered by their college
...
The two compulsory Ability Enhancement Courses (AECs): AE1 (Environmental Sciences) and
AE2 (English Communication) will be of four credits each (theory only)
...
Page 3 of 109
COURSES OFFERED UNDER B
...
APPLIED PHYSICAL SCIENCES WITH
INDUSTRIAL CHEMISTRY PROGRAMME (CBCS)
Semeste
r
I
Course offered
Ability Enhancement
Compulsory Course-I
Core Course Industrial
Chemistry-I
Core Course Industrial
Chemistry -I Practical
Core Course Chemistry-I
Core Course Chemistry-I
Practical
II
Core Course Mathophysics-I
Core Course Mathophysics -I
Practical
Ability Enhancement
Compulsory Course-II
Core Course Industrial
Chemistry-II
Core Course Industrial
Chemistry -II Practical
Core Course Chemistr -II
Core Course Chemistry-II
Practical
III
Core Course Mathophysics-II
Core Course Mathophysics-II
Practical
Core Course Industrial
Chemistry -III
Core Course Industrial
Chemistry - III Practical
Course name
Credits
English/ MIL Communications/
Environmental Science
Industrial Chemicals and
Environment
Industrial Chemicals and
Environment
Atomic structure, bonding, General
Organic Chemistry & Aliphatic
hydrocarbons
Atomic structure, bonding, General
Organic Chemistry & Aliphatic
hydrocarbons
Mechanics
Mechanics
4
English/ MIL Communications/
Environmental Science
Fossil Fuels, Cleansing Agents and
Food Additives
Fossil Fuels, Cleansing Agents and
Food Additives
Chemical Energetics, Equilibria &
Functional Group Organic
Chemistry-1
Chemical Energetics, Equilibria &
Functional Group Organic
Chemistry-1
Calculus and Matrices
Calculus and Matrices
4
Inorganic Materials of Industrial
Importance
Inorganic Materials of Industrial
Importance
4
4
2
4
2
4
2
4
2
4
2
4
2
2
Page 4 of 109
Core Course Chemistry - III
Core Course Chemistry - III
Practical
IV
Core Course Mathophysics –
III
Core Course Mathophysics –
III Practical
Skill Enhancement Course-I
Skill Enhancement Course –I
Practical/Tutorials*
Core Course Industrial
Chemistry -IV
Core Course Industrial
Chemistry- IV Practical
Core Course Chemistry-IV
Core Course Chemistry-IV
Practical
V
Core Course MathophysicsIV
Core Course MathophysicsIV Practical
Skill Enhancement Course-II
Skill Enhancement Course-II
Practical/Tutorials*
Discipline Specific Elective -1
Discipline Specific Elective -1
Practical/Tutorials*
Discipline Specific Elective -I
Discipline Specific Elective –I
Practical/Tutorials*
Solutions, Phase Equilibria,
Conductance, Electrochemistry &
Functional Group Organic
Chemistry -II
Solutions, Phase Equilibria,
Conductance, Electrochemistry &
Functional Group Organic
Chemistry –II
Algebra
4
Algebra
2
2
4
2
2
Pharmaceuticals,
Cosmetics,
Perfumes & Pesticides
Pharmaceuticals, Cosmetics,
Perfumes & Pesticides
Chemistry of s- and p- block
elements, States of matter &
Chemical kinetics
Chemistry of s- and p- block
elements, States of matter &
Chemical kinetics
Wave and Optics
4
Wave and Optics
2
2
4
2
4
2
2
Industrial Chemistry
Industrial Chemistry
4
2
Chemistry of d-Block elements,
Quantum Chemistry &
Spectroscopy
Chemistry of d-Block elements,
Quantum Chemistry &
4
2
Page 5 of 109
VI
Discipline Specific Elective -I
Discipline Specific Elective I
Practical/Tutorials*
Skill Enhancement Course-III
Skill Enhancement Course-III
Practical/Tutorials*
Discipline Specific Elective -II
Discipline Specific Elective –II
Practical/Tutorials*
Discipline Specific Elective -II
Discipline Specific Elective –II
Practical/Tutorials*
Discipline Specific Elective -II
Discipline Specific Elective –
II Practical/Tutorials*
Skill Enhancement Course-IV
Skill Enhancement Course-IV
Practical/Tutorials*
Spectroscopy
Mathophysics - Physics
Mathophysics - Physics
4
2
2
2
Industrial Chemistry
Industrial Chemistry
4
2
Chemistry
Chemistry
4
2
Mathophysics - Maths
Mathophysics - Maths
4
2
Total Credits
* Wherever there is practical there will be no tutorials and vice –versa
2
2
132
Page 6 of 109
DETAILS OF COURSES
CORE COURSES: Industrial Chemistry
I
...
Industrial Chemicals and Environment
Industrial Chemistry -Fossil Fuels, Cleansing Agents and Food Additives
III
...
Industrial Chemistry -4:Pharmaceuticals, Fermentation, Pesticides & Perfumes
CORE COURSES: Chemistry
I
...
III
...
Chemistry of s- and p-block elements, States of matter & Chemical
kinetics
CORE COURSES: Mathophysics
Mechanics
I
...
Calculus and Matrices
III
...
Wave and Optics
DISCIPLINE SPECIFIC ELECTIVES: Industrial Chemistry (Any two)
1
...
Industrial Chemicals and Environment
3
...
Inorganic Materials of Industrial Importance
5
...
Dissertation
Page 7 of 109
DISCIPLINE SPECIFIC ELECTIVES Chemistry (two)
1
...
Organometallics, Bio-inorganic Chemistry, Polynuclear Hydrocarbons and UV,
IR Spectroscopy
3
...
Analytical Methods in Chemistry
5
...
Novel Inorganic Solids
7
...
Molecules of life
9
...
Electricity and Magnetism
2
...
Medical Physics
4
...
Calculus and Geometry
SKILL ENHANCEMENT COURSE Industrial Chemistry (two)
1
...
Basic Analytical Chemistry
3
...
Chemical Technology and Society
5
...
Green Methods in Chemistry
7
...
Business Skills for Chemist
2
...
Pharmaceuticals Chemistry
4
...
Fuel Chemistry
Learning Outcome- based Approach to Curriculum Planning
● Introduction
The learning outcome - based approach for B
...
Applied Physical Science with industrial
chemistry is to design curriculum framework to suit the requirements of the various
industries
...
The core courses in
Chemistry, mathematics and physics are designed to build strong foundation in theory and
principles useful for practical applications
...
The program also offers wide range of discipline
specific electives, skill enhancement, and compulsory Ability Enhancement and
Environmental science courses to prepare students to improve their skills required in
academic, research and in industrial projects using greener technology which are
environmental friendly
...
The main objective of this degree course is to produce graduates
Page 9 of 109
with enhanced skills, knowledge and research aptitude to carry out higher studies or research
and development in the various industrial areas
...
Overall, the course offers basic
foundation in chemistry, physics and maths which enables the students to understand the
concepts in chemical processing, engineering and industrial management
...
● Capability to demonstrate knowledge and understanding of major chemistry concepts,
theoretical principals and experimental findings and ability to use modern
instrumentation techniques with chemical analysis and separation
...
● Ability to transfer chemical products and techniques developed at laboratory scale to the
industrial level
...
● Understanding of various methods of safe handling, storages and health hazards of
chemicals and processes used in the laboratories
...
● Enabled with quality of team work and strength of interacting with people from diverse
backgrounds
...
● Excellent communication skills to transmit complex technical information related to
chemistry in a clear and concise written and verbal manner as oral presentations and
compilation in the form of scientific reports
...
● Cultivated independent thinking and is able to integrate knowledge from other disciplines
to fit various industrial areas
...
Learning outcome of the program
On successful completion of the course of B
...
Programme Industrial Chemistry the student
will be able to:
⮚
Describe the chemical industry and identify the distinguishing features of its
component,
⮚
Explain the importance and roles of process optimization in chemical processing,
⮚
Describe the industrial production of a number of important organic and inorganic
compounds/chemicals,
⮚
Evaluate environmental issues pertaining to the chemical industry,
⮚
Able to use modern instrumentation techniques for chemical analysis and separation,
⮚
Able to communicate the results of their work to chemists and non-chemists
...
In this course fundamental and applied aspects of organic, inorganic, physical and analytical
chemistry as well as key major concepts, theoretical principles and experimental findings in
industrial chemistry will be covered
...
Further, they will be proficient in application of current aspects of industrial
chemistry
...
Page 11 of 109
Laboratory Skills: Students will become efficient in using Standard operating procedures and
will be well versed with the regulations for safe handling and use of chemicals
...
They will undertake hands on lab work and practical activities which develop problem solving
abilities required for successful career in pharmaceuticals, chemical industries, teaching research,
environmental monitoring, product quality, consumer good industries, food products, cosmetic
industries, oils and lubricants industries, fuels, petrochemicals and energy sector, etc
...
They will be able to identify and explore new areas of
research and planning, execute and report the results of an experiment or investigation, critical
thinking and scientific inquiry in the performance, design
...
Inquisitiveness: This course will be able to enhance the ability to assimilate, discuss scholarly
articles and research papers showcasing interdisciplinary areas of industrial chemistry and
capability for asking questions relating to issues and problems in the field of industrial
chemistry
...
They could interact with peers from diverse
backgrounds with developed confidence to lead a team
...
They will become efficient in using standard operating
procedures and will be proficient with safe handling regulations and use of chemicals
...
Page 12 of 109
ICT enabled: Students will be trained to use modern library searching and retrieval methods to
obtain information about a topic, relating to Industrial chemistry
...
Lifelong learners: Students will be capable of self-paced and self-directed learning aimed at
personal development and for improving knowledge/skill development
...
Career Opportunity: Graduates with B
...
Programme Industrial Chemistry, will have
possibility to find employment in government departments, research and development institutes,
production, biotechnology, quality control, pharmaceutical industry, process industry, fertilizer
production industry, plastics industry, pulp and paper industry, tanning industry, consumer
industry, oil and petroleum industry, textile industry, dyes and paints industry, cosmetics
industry, cement industry, glass industry, water purification and waste water purification
engineering including forensic science and patents, defence, education and research, and areas
related to polymer chemistry
...
After their post-graduation, they may opt for Ph
...
in multidisciplinary areas
...
The B
...
Program Industrial Chemistry course is aims to make the students proficient in
industrial chemistry through the transfer of knowledge in the classroom as well as in the
laboratory
...
In the classroom this will be done through blackboard
and chalk lectures, charts, PowerPoint presentations, and the use of audio visual resources that
are available on the internet such s virtual lab
...
A variety of approaches to teaching-learning process, including
lectures, seminars, tutorials, workshops, peer teaching and learning, practicum and project-based
learning, field-based learning, substantial laboratory-based practical component and experiments,
open-ended project work, technology-enabled learning, internship in industry and research
establishments etc
...
Problem-solving skills and higher-order skills of reasoning
and analysis will be encouraged through teaching strategies
...
An interactive mode of teaching will be used
...
A
problem solving approach will be adopted wherever suitable
...
Emphasis on laboratory work is particularly important keeping in mind
the practical nature of the subject, and the time devoted to practical will enable the students to
better understand the applications of the different courses
...
Assessment Methods
The assessment of students achievements in Industrial Chemistry will be aligned with the
course/program learning outcomes and the academic and professional skills that the program is
designed to develop
...
A variety of appropriate assessment methods within the disciplinary area of
industrial chemistry will be used
...
Exchange program with different colleges and universities from different parts of the state
will be provided
...
Besides
standardized tests, interim benchmarks, daily assessments, observations, interviews and
formal assessments to individualize interventions will be carried out to enhance overall
student performance
...
Page 15 of 109
SEMESTER-I
CORE COURSE INDUSTRIAL CHEMISTRY-I
INDUSTRIAL CHEMICALS & ENVIRONMENT
(Industrial Chemistry1-4(i))
Core Course - (CC) Total Credit:6
Theory: Credits-04, Lectures-60
Practical: Credits-02, Lectures-60
Course Objective
The aim of this course is to make students aware of different industrial processes in detail
...
The
analytical approach of this course is to enhance the reasoning and to understand the mechanical part of
the industry
...
Course Learning Outcomes
Unit 1
To know the various purification techniques used in industries like distillation, absorption,
adsorption and solvent extraction
...
Understand and develop efficacy in handling and preparation of frequently used inorganic
chemicals like acids, bases, oxidizing and disinfecting chemicals
...
Qualitative and quantitative measurements of water treatment, conservation and handling of
industrial effluent
...
An introduction into the scope of different types of equipment
needed in chemical technology, including reactors, distillation columns, extruders, pumps, mills,
emulgators
...
(15 Lectures)
Page 16 of 109
Unit 2
Industrial Gases and Inorganic Chemicals
(a) Industrial Gases: Large scale production, uses, storage and hazards in handling of the following
gases: oxygen, nitrogen, argon, neon,helium, hydrogen, acetylene, carbon monoxide, chlorine, fluorine,
sulphur dioxide and phosgene
...
(20 Lectures)
Unit 3
Environment
(a) Air Pollution: Pollutants and their sources, pollution by SO 2, CO2, CO, NOx, H2S and other foul
smelling gases
...
Green house effect
and Global warming, Ozone depletion by oxides ofnitrogen, chlorofluorocarbons and Halogens, Removal
of sulphur from coal
...
(b) Water pollution and Water Quality Standards: Pollutants and their sources, Effluent treatment plants
(primary, secondary and tertiary treatment)
...
Sludge disposal
...
Water treatment and purification
(reverse osmosis, electro dialysis, ion exchange)
...
(25 Lectures)
Practical
1
...
3
...
5
...
7
...
9
...
Determination of Chemical Oxygen Demand (COD)
Determination of Biological Oxygen Demand (BOD)
Percentage of available chlorine in bleaching powder
...
(AgNO3and potassium chromate)
2Estimation of total alkalinity of water samples (CO3 , HCO3 ) using double titration method
...
A survey based study on common bio-indicators of pollution and SPM in air samples
...
References
1
...
Stocchi: Industrial Chemistry, Vol-I, Ellis Horwood Ltd
...
Page 17 of 109
2
...
4
...
6
...
A
...
S
...
Dara: A Textbook of Engineering Chemistry, S
...
New Delhi
...
K
...
S
...
Khopkar, Environmental Pollution Analysis: Wiley Eastern Ltd, New Delhi
...
K
...
There are different components
of learning and the capacity of each learner varies
...
e
...
Different ways of
teaching include classical board teaching method, visual conceptual method, application based practical
demonstration of the concept etc
...
Keywords: Industrial Chemicals, Purification techniques, Handling of acids and bases, air pollutants,
Industrialeffluents
...
Assessment can be in question
answer form, quiz form, project form etc
...
Atomic Structure, Bonding, General Organic & Aliphatic Hydrocarbons
Total Credits: 06
(Credits: Theory-04, Practicals-02)
(Total Lecture: Theory- 60, Practicals-60)
Objectives:
The course reviews the structure of the atom, which is a necessary pre-requisite in understanding
the nature of Chemical Bonding in compounds
...
It discusses the Periodicity in properties with reference to
the sand p block, which is necessary in understanding their group chemistry
...
To establish the
Page 18 of 109
applications of these concepts, the functional groups- alkanes, alkenes, alkynes and aromatic
hydrocarbons- are introduced
...
Learning Outcomes:
By the end of the course, the students will be1
...
2
...
3
...
4
...
5
...
Unit 1
Section A: Inorganic Chemistry-1 (30 Periods)
Atomic Structure
Review of: Bohr’s theory and its limitations, Heisenberg Uncertainty principle
...
Hydrogen atom spectra
...
What is
Quantum mechanics? Time independent Schrodinger equation and meaning of various terms in it
...
Radial and angular parts of the hydogenic wavefunctions
(atomic orbitals) and their variations for 1s, 2s, 2p, 3s, 3p and 3d orbitals (Only graphical representation)
...
Radial distribution functions and the concept of the most
probable
distance with special reference to 1s and 2s atomic orbitals
...
Shapes of s, p and d atomic orbitals, nodal planes
...
Rules for filling electrons in various orbitals, Electronic configurations of the atoms
...
Relative energies of atomic orbitals, Anomalous
electronic configurations
...
Energy considerations in ionic bonding, lattice energy
and solvation energy and their importance in the context of stability and solubility of ionic compounds
...
Fajan’s rules, ionic character in covalent compounds, bond
moment, dipole moment and percentage ionic character
...
Concept of resonance and resonating structures in various inorganic and organic compounds
...
(Lectures:16)
Section B: Organic Chemistry-1
Unit 3 Fundamentals of Organic Chemistry
Electronic Displacements: Inductive Effect, Electromeric Hyperconjugation
...
Effect, Resonance and Reaction intermediates: Carbocations, Carbanions and free radicals
...
(Lectures :8)
Unit 4:
Stereochemistry
Conformations with respect to ethane, butane and cyclohexane
...
Concept of chirality (upto two carbon atoms)
...
Threo and
erythro; D and L; cis - trans nomenclature; CIP Rules: R/ S (for upto 2 chiral carbon atoms) and E / Z
Nomenclature (for upto two C=C systems)
...
Alkanes: Preparation: Catalytic
hydrogenation,
Wurtz
Grignard reagent
...
reaction,
Kolbe’s
synthesis,
Page 20 of 109
Alkenes: Preparation: Elimination reactions: Dehydration of alcohols and dehydrohalogenation of alkyl halides
(Saytzeff’s
rule);
cis
alkenes
(Partial
catalytic
hydrogenation)
and
trans
alkenes (Birch
reduction)
...
KMnO4)
andtrans-addition
(bromine),
Addition of
HX
(Markownikoff’sand anti-Markownikoff’s addition), Hydration, Ozonolysis, oxymecuration-demercuration,
Hydroboration-oxidation
...
Reactions: formation of metal acetylides and acidity
of alkynes, addition of bromine and alkaline KMnO4, ozonolysis and oxidation with hot alk
...
Hydration to
form carbonyl compounds
(Lectures :12)
Practical:
Section A: Inorganic Chemistry - Volumetric Analysis
1
...
2
...
3
...
4
...
5
...
Section B: Organic Chemistry
1
...
2
...
P
...
P
...
Detection of extra elements (N, S, Cl, Br, I) in organic compounds
4
...
References:
Theory:
J
...
Lee: A new Concise Inorganic Chemistry, E L
...
S
...
A
...
Wilkinson: Basic Inorganic Chemistry, John Wiley
...
James E
...
T
...
Graham Solomon: Organic Chemistry, John Wiley and Sons
...
E
...
Eliel: Stereochemistry of Carbon Compounds, Tata McGraw Hill
...
L
...
I & II), E
...
B
...
R
...
Morrison & R
...
Boyd: Organic Chemistry, Prentice Hall
...
S
...
Chand
Atkins, Overton, Rourke, Weller, Armstrong, Shriver and Atkins Inorganic Chemistry, Oxford
Practical:
Vogel’s Qualitative Inorganic Analysis, A
...
Vogel, Prentice Hall, 7th Edition
...
I
...
Textbook of Practical Organic Chemistry, A
...
Vogel , Prentice Hall, 5th Edition
...
G
...
& B
...
Saunders, Orient Longman, 1960
...
Hands-on learning using 3-D models, videos, presentations, seminars
Technology driven Learning
...
Keywords
Atomic structures, quantum numbers, lattice energy, stereochemistry, resonance, inductive effect,
hyperconjugation
SEMESTER-II
INDUSTRIAL CHEMISTRY-FOSSIL FUELS, CLEANSING AGENTS AND
FOOD ADDITIVES
(Industrial Chemistry1--4(ii))
Core Course - (CC) Credit:6
Theory: Credits-04, Lectures-60
Practical: Credits-02, Lectures-60
Course Objective
After studying this course, student shall be able to understand the different aspects of industrial processes of fossil fuels in
detail
...
The analytical approach of this course is to enhance the reasoning and to understand
the mechanical part of the industry
...
An understanding the role of Petroleum and Petrochemical Industry, Composition, applications, processcracking
...
Petrochemical
...
Types of lubricants their property based on viscosity
index, cloud point, pore point and applications of lubricant in Industry
...
An increasing demands of food additives- Merit and Demerits of synthetic and natural colouring, flavouring and
sweetening agents
...
Classification of fuels and their calorific
value
...
Coal gas, producer gas and water gas—composition and their uses
...
(b) Petroleum and Petrochemical Industry: Composition of crude petroleum, Refining and different types of petroleum
products and their applications
...
Petrochemicals: Vinyl acetate, Propylene oxide, Isoprene, Butadiene,
Toluene and Xylene
...
(40 Lectures)
Unit-2
Oils and Fats : Classification of oils, fat splitting, distillation of completely miscible and non-miscible oils, hydrogenation
of oils, rancidity, saponification value, iodine number, acid value, Soap and Synthetic Detergent, preparation of soap and
detergent, different types of soap and their composition, surfactants (LAS, ABS, LABS), detergent binders and
builders
...
Determination of alkali in water samples and soaps
...
Extraction of essential oils from flowers and fruits by soxhlet extraction method
...
Extraction of natural coloring and flavoring agent from flowers and fruits
...
Determination of iodine value of the oils/ fats
...
Determination of saponification value of the oils/ fats
...
Determination of acid value of the oils/ fats
...
Testing of turmeric powder, milk and mustard oil for adulterants
...
Estimation of glucose in food samples
...
Estimation of hardness of water by titration with soap solution
...
Preparation of soap
...
O
...
Vermani, A
...
Narula: Industrial Chemistry, Galgotia Publications Pvt
...
, New Delhi
...
S
...
Bhatia: Chemical Process Industries, Vol
...
3
...
C
...
Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi
...
R
...
Venkappayya, S
...
5
...
K
...
Chemical Energetics, Equillibria and Functional Organic Chemistry-I
Total Credits: 06
(Credits: Theory-04, Practicals-02)
(Total Lectures: Theory- 60, Practicals-60)
Objectives:
The objective of this paper is to develop basic understanding of the chemical energetics, laws of
thermodynamics, chemical and ionic equilibrium
...
To acquaint students with the functional group approach to study organic
compounds
...
To establish a relationship
between the structure and physical and chemical characteristic of compounds containing these functional
groups
...
Students will be able to understand concept of pH and its effect on the various physical and chemical
properties of the compounds
...
This course will help students to understand the fundamentals of functional group chemistry through
the study of methods of preparation, properties and and chemical reactions with underlying
mechanism
...
Unit 1:
Page 25 of 109
Chemical Energetics
Review of thermodynamics and the Laws of Thermodynamics
...
Concept of standard state and standard
enthalpies of formations, integral and differential enthalpies of solution and dilution
...
Variation of
enthalpy of a reaction with temperature – Kirchhoff’s equation
...
(8 Lectures)
Unit 2:
Chemical Equilibrium
Free energy change in a chemical reaction
...
Distinction between G and Go, Le Chatelier’s principle
...
(8 Lectures)
Unit 3:
Ionic Equilibria
Strong, moderate and weak electrolytes, degree of ionization, factors affecting degree of ionization, ionization
constant and ionic product of water
...
Salt
hydrolysis-calculation of hydrolysis constant, degree of hydrolysis and pH for different salts
...
Solubility and solubility product of sparingly soluble salts – applications of solubility product principle
...
Preparation: Methods of preparation of benzene from phenol, benzoic acid, acetylene and benzene sulphonic
acid
...
( 7 Lectures)
Page 26 of 109
Unit 5:
Alkyl and Aryl Halides
A) Alkyl Halides (upto 5 carbons):
Structure of haloalkanes and their classification as 1⁰, 2⁰ & 3⁰
...
Stereochemical aspects of each type
...
B) Haloarenes :
Structure and resonance
Preparation: Methods of preparation of chloro, bromo & iodobenzene from benzene (electrophilic substitution),
and from aniline (Sandmeyer and Gattermann reactions)
Reaction: Nucleophilic Aromatic Substitution by OH group (Bimolecular Displacement Mechanism)
...
Reaction with strong bases like KNH2 in NH3 (or NaNH2/NH3)
...
Relative reactivity and strength of C-X bond
in alkyl, allyl, benzyl, vinyl and aryl halides
(12 Lectures)
Unit 6:
Alcohols, Phenols and Ethers
A) Alcohols (upto 5 Carbon) :
Structure and classification of alcohols as 1⁰, 2⁰ & 3⁰
...
Reactions: Acidic character of alcohols and reaction with sodium, with HX (Lucas Test), esterification,
oxidation (with PCC, alk KMnO4, acid K2Cr2O7 and conc HNO3), Oppeneauer Oxidation
...
C) Phenols: Structure, relative reactivity and comparison of acidity of alcohols and phenols and factors
affecting the acidity of phenols
...
Reactions: Directive influence of OH group and Electrophilic substitution reactions, viz
...
Reaction due to OH group : Schotten-Baumann reaction
D) Ethers (aliphatic & aromatic) :
Williamson's ether synthesis, Cleavage of ethers with HI (SN1 & SN2 mechanisms)
(11 Lectures)
Practical:
Section A: Physical Chemistry
Energetics:
1
...
2
...
3
...
4
...
5
...
Ionic equilibria and pH measurements:
1
...
2
...
Section B: Organic Chemistry
Preparations: (Mechanism of various reactions involved to be discussed)
1
...
2
...
(b)Benzoylation of amines/phenols
4
...
References:
Theory:
W
...
Peter Sykes: A Guide Book to Mechanism in Organic Chemistry, Orient Longman
...
L
...
I & II), E
...
B
...
R
...
Morrison & R
...
Boyd: Organic Chemistry, Prentice Hall
...
S
...
Chand
...
M
...
G
...
Castellan: Physical Chemistry 4th Edn
...
J
...
Kotz, P
...
Treichel & J
...
Townsend: General Chemistry Cengage Lening India Pvt
...
, New
Delhi (2009)
...
H
...
Narosa (1998)
...
H
...
Macmillan Publishing Co
...
Practical:
A
...
Vogel: Textbook of Practical Organic Chemistry, 5th edition, Prentice-Hall
...
G
...
C
...
B
...
Khosla, Senior Practical Physical Chemistry, R
...
Teaching Learning Process:
The teaching learning process will involve the blended learning technique along with traditional chalk
and black board method wherever required
...
Students are encouraged to participate actively in the classroom through regular presentations on
curriculum based topics
...
Keywords:
Hydrocarbons, Haloalkanes and haloarenes, Alcohols, Phenols and Ethers
...
This paper is designed in such a way that it will enrich students with the knowledge of various type of surface
coatings, Fillers, Thinners, Enamels, Emulsifying agents
...
Course Learning Outcomes
To establish an appreciation of the role of inorganic chemistry in the chemical sciences
...
Students develop skills to estimate various components of fertilizers
...
Skilled in scientific method of planning, developing, conducting, reviewing and reporting experiments
...
Knows scientific methods employed in inorganic chemistry
...
Manufacture
and
processing
of
glass
...
non-silicate
of
the
safety
(b) Ceramics: Ceramic, their types and manufacture
...
(c)
Cement:
Classification
of
cement,
cement and the setting process, quick setting cements
ingredients
and
their
role
Manufacture
of
(20 Lectures)
Unit 2
Surface Coatings
Objectives of surface coatings, preliminary treatment of surface and classification of surface coatings
...
Oil paint, Vehicle oils, modified oils, Pigments,
toners and lakes pigments, Fillers, Thinners, Enamels, emulsifying agents
...
Metallic coatings (electrolytic and electroless), metal spraying and anodizing
...
Working of following batteries: Pb acid, Li-Battery, Solid state electrolyte battery
...
(10 Lectures)
Unit 4
Alloys
Classification of alloys, Ferrous and Non- Ferrous alloys, Specific properties of elements in alloys
...
desulphurization
Composition and properties of different types of steel
...
(3 Lectures)
Practical
1
...
3
...
5
...
7
...
Preparation of paints
...
Analysis of (Cu, Ni) (Cu, Zn) in alloy or synthetic samples
...
Study the loss of raw iron in acidic medium
...
Page 31 of 109
References
1
...
Stocchi: Industrial Chemistry, Vol-I, , Ellis Horwood Ltd
...
2
...
M
...
W
...
3
...
D
...
K
...
R
...
4
...
A
...
5
...
C
...
Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi
...
R
...
Venkappayya, S
...
7
...
K
...
Keywords: Glass, Ceramics, Cements, Surface coatings, Alloys, Primary and Secondary batteries, Fullerenes
Solutions, Phase Equillibrium, Conductance, Electrochemistry and
Functional Group Organic Chemistry-II
Total Credits: 06
(Credits: Theory-04, Practicals-02)
(Total Lecture: Theory- 60, Practicals-60)
Objectives:
In Section A of this course students will learn about ideal and non-ideal solutions, Raoult's law, azeotrpes,
concept of EMF of a cell and measurement of emf of a cell
...
In Section B of this course, students will learn: carboxylic acids and their derivatives,
key biomolecules like carbohydrates, amino acids and proteins
...
Hoffman and Saytzeff elimination
...
Concept of zwitterion and isoelectric point in amino acids
...
Reactions of carbohydrates
...
To understanding different complex reactions
Synthesis and designing of new drugs
...
Vapour pressure -composition and temperature-composition curves of ideal and non-ideal solutions
...
Lever rule
...
Partial miscibility of liquids: Critical solution temperature; effect
of impurity on partial miscibility of liquids
...
Nernst
distribution law and its applications, solvent extraction
...
Gibbs Phase Rule and
its thermodynamic derivation
...
Phase diagrams of one component systems (water and sulphur) and two component systems
involving eutectics, congurent and incongurent melting points (lead-silver, FeCl3-H2O and Na-K only)
...
Kohlrausch Law of independent migration of ions
...
Ionic mobility
...
Conductometric titrations (only acid-base)
...
Concept of EMF of a cell
...
Nernst equation and
its importance
...
Standard electrode potential
...
Thermodynamics of
a reversible cell, calculation of thermodynamic properties: G,H and S from EMF data
...
Concentration cells with transference and without transference
...
pH determination using hydrogen electrode and quinhydrone electrode
...
(10 Lectures)
Section B: Organic Chemistry-3 (30 Lectures)
Unit 5:
Functional group approach for the following reactions (preparations, physical & chemical properties) to be
studied in context to their structure with mechanism
...
Reactions: Hell-Volhard Zelinsky
reaction, acidity of carboxylic acids, effect of substituion on acid strength
...
Reactions: Relative reactivities of acid derivatives towards nucleophiles, Reformatsky reaction,
Perkin condensation
...
Reactions: Hofmann vs
Saytzeff elimination, carbylamine test, Hinsberg test, reaction HNO2, Schotten-Baumann reaction
...
Diazonium salt Preparation:
from aromatic amines Reactions: conversion to benzene, phenol and dyes
...
Preparation: Strecker
synthesis, Gabriel phthalimide synthesis
...
Overview of primary, secondary, tertiary and quarternary structure
of proteins
...
Synthesis of simple peptides (upto dipeptides) by
N-protection (t-butyloxycarbonyl and phthaloyl) & C-activating groups and Merrifield solid-phase synthesis
...
Glucose and fructose (open chain and cyclic
structure)
...
Structure of disaccharides (sucrose, cellobiose,
maltose, lactose) and polysacharides (starch and cellulose) excluding thir structure elucidation
...
Construction of the phase diagram of a binary system (simple eutectic) using cooling curves
...
Determination of critical solution temperature and composition of phenol water system and study the effect of
impurities on it
...
Determination of cell constant
...
Determination of equivalent conductance, degree of dissociation and dissociation constant of a weak acid
...
Perform the following conductometric titrations: a) Strong acid vs strong base b) Weak acid vs strong base
...
Systematic qualitative analysis of organic compounds possessing monofunctional groups: alcohols, phenols,
carbonyl, acids, nitro, amide,amines, hydrocarbons and halo hydrocarbons and preparation of one derivative
...
Determination of the concentration of glycine solution by formylation method
...
M
...
G
...
Castellan: Physical Chemistry 4th Ed
...
R
...
Morrison and R
...
Boyd; Organic Chemistry, Dorling Kindersley (India) Pvt
...
(Pearson Education)
...
L
...
Ltd
...
Teaching Learning Process:
Conventional teaching methods as well as power point presentations
...
Assessment Methods:
Student evaluation will be done on the basis of regular class test, assignments and presentations during the
course
...
SEMESTER IV
INDUSTRIAL CHEMISTRY-4: PHARMACEUTICALS, FERMENTATION,
PESTICIDES AND PERFUMES
(IndustrialChemistry1)
Core Course - (CC) Credit:6
Theory: Credits-04, Lectures-60
Practical: Credits-02, Lectures-60
Course Objective
The objectives of this paper are to provide basic knowledge of chemistry of pharmaceuticals , cosmetics,
perfumes and pesticides considering their importance for human beings
...
The paper has
been designed to impart the theoretical and practical knowledge on the basic chemistry and uses of
various pharmaceuticals, cosmetic products and pesticides
...
Students will have sound knowledge of pharmaceuticals, cosmetics, perfumes and pesticides
...
Students will become well equipped to design, carry out, record and analyze the industrial preparations
3
...
4
...
5
...
6
...
Unit 1
Drugs and Pharmaceuticals
Drug discovery, design and development; Retrosynthetic approach (with any two examples)
...
Ibuprofen), antibiotics (Penicillin, Cephalosporin, Chloromycetin, Streptomycin and Chloramphenicol);
antibacterial and antifungal agents (Sulphonamides, Sulphanethoxazol, Sulphacetamide, Trimethoprim); antiviral agents
(Acyclovir)
...
(20 Lectures)
Unit 2
Cosmetics and Perfumes
Introduction to cosmetics and perfumes, preparation and uses of the following: Hair dye, hair spray
...
Sun-tan
lotions, face powder, lipsticks
...
Essential oils and their importance in cosmetic industries with reference to Eugenol
...
Structure activity relationship, synthesis and technical manufacture, uses of representative pesticides in the following
classes: Organochlorines (DDT, Gammaxene), Organophosphates (Malathion, Parathion), Carbamates (Carbofuran and
carbaryl), Quinones (Chloranil), Anilides (Alachlor and Butachlor)
...
Production of (i) Ethyl alcohol and citric acid; (ii) Lysine, Glutamic acid, Vitamin
B2, Vitamin B12, Vitamin C
...
2
...
4
...
6
...
8
...
10
...
Preparation of talcum powder
...
Preparation of nail enamel
Preparation of hair remover
...
Preparation of Aspirin and its analysis
...
To calculate acidity/alkalinity in given sample of pesticide formulations as per BIS specifications
...
Preparation of paracetamol
...
2
...
4
...
6
...
O
...
Vermani, A
...
Narula: Industrial Chemistry, Galgotia Publications Pvt
...
, New Delhi
...
C
...
I & II, CBS Publishers, New Delhi
...
C
...
Jain: Engineering Chemistry, Dhanpat Rai & Sons, Delhi
...
Gopalan, D
...
Nagarajan: Engineering Chemistry, Vikas Publications, New Delhi
...
K
...
Handbook of Cosmetic Science and Technology; Edited by Andre´ O
...
Maibach;
Informal Healthcare;2009, ISBN 978-1-4200-6963-1
Page 37 of 109
8
...
10
...
12
...
14
...
Text Book of Cosmetics; Dr Akanksha Garud, Dr PK Sharma, Dr Navneet Garud;Pragati Prakashan; 2012,
ISBN 978-93-5006-691-1
Pharmaceutics and Cosmetics; Praveen K
...
Gupta; Pragati Prakashan;2011 ISBN 978-818398-995-4
Poucher's perfumes , Cosmetic and Soap, H
...
Flick, Noyes Publications William Andrew Publishing, ISBN:
0-8155-1454-9
Natural Ingredients for Cosmetics; EU Survey 2005
Formulation Guide for Cosmetics; The Nisshin OilliO Group, Ltd
...
There are different components
of learning and the capacity of each learner varies
...
e
...
Different ways of
teaching include classical board teaching method, visual conceptual method, application based practical
demonstration of the concept etc
...
Assessment Methods
The effectiveness of learning can be judged by assessing the students
...
Students should also engage in selfassessment and peer group learning activities
...
To understand the trends exhibited by s and p block elements and their compounds
with emphasis on synthesis, structure, bonding and applications
...
Learning Outcomes:
The students will be able:
To learn the fundamental principles of metallurgy
...
To define the average and instantaneous rate of reaction
...
To discuss the surface tension and viscosity of liquids and determination of surface tension by
using Stalagmometer and coefficient of viscosity by Ostwald Viscometer
To discuss different forms of solids, symmetry elements, unit cells and crystal systems
...
To be able to define rate of reactions and the factors that affect the rates of reaction
...
g
...
and their determination
...
Ellingham diagrams for reduction
of metal oxides using carbon as reducing agent
...
Mond's process and Zone Refining
...
Allotropy in C, S,
and P
...
Compounds of s- and p-Block Elements
Diborane and concept of multicentre bonding
Structure, bonding and their important properties like oxidation/reduction, acidic/basic nature of the
following compounds and their applications in industrial and environmental chemistry
...
Halides and oxohalides: PCl3, PCl5, SOCl2 and SO2Cl2
(26 Lectures)
Unit 3:
Section B: Physical Chemistry
(30 Lectures)
Kinetic Theory of Gases
Postulates of Kinetic Theory of Gases and derivation of the kinetic gas equation
...
van der Waals
equation of state for real gases
...
Critical phenomena,
critical constants and their calculation from van der Waals equation
...
Maxwell Boltzmann distribution laws of molecular velocities and molecular energies (graphic
representation – derivation not required) and their importance
...
Most probable, average and root mean square
velocities (no derivation)
...
Viscosity of gases and effect of temperature and pressure
on coefficient of viscosity (qualitative treatment only)
...
Viscosity of a liquid and determination of
coefficient of viscosity using Ostwald viscometer
...
(3 Lectures)
Page 40 of 109
Unit 5:
Solids
Forms of solids
...
Laws of Crystallography - Law of constancy of interfacial angles
...
Miller indices
...
Structures of NaCl, KCl and
CsCl (qualitative treatment only)
...
Glasses and liquid crystals
...
Effect of temperature, pressure, catalyst and other factors on reaction rates
...
Derivation of integrated rate equations for zero, first and second order
reactions (both for equal and unequal concentrations of reactants)
...
General methods for
determination of order of a reaction
...
Theories of Reaction Rates: Collision theory and Activated Complex theory of bi-molecular reactions
...
(11 Lectures)
Practical:
Section A: Inorganic Chemistry
Semi-micro qualitative analysis of mixtures using H2S or any other scheme- not more than four ionic species
(two anions and two cations and excluding insoluble salts) out of the following:
Cations : NH4+, Pb2+, Bi3+ , Cu2+ , Fe3+, Al3+, Co2+ , Ni2+, Mn2+, Zn2+, Ba2+, Sr2+, Ca2+, K+
...
(Spot tests should be carried out wherever feasible)
Section B: Physical Chemistry
(I) Surface tension measurement (use of organic solvents excluded)
...
b) Study of the variation of surface tension of a detergent solution with concentration
...
a) Determination of the relative and absolute viscosity of a liquid or dilute solution using an Ostwald
viscometer
...
b) Study of the variation of viscosity of an aqueous solution with concentration of solute
...
b) Saponification of ethyl acetate
...
M
...
G
...
Castellan: Physical Chemistry 4th Edn
...
J
...
Kotz, P
...
Treichel & J
...
Townsend: General Chemistry Cengage Lening India Pvt
...
, New
Delhi (2009)
...
H
...
Narosa (1998)
...
H
...
Macmillan Publishing Co
...
D
...
L
...
S
...
A
...
Wilkinson: Basic Inorganic Chemistry, John Wiley
...
F
...
W
...
Gary Wulfsberg: Inorganic Chemistry, Viva Books Pvt
...
Miessler, G
...
& Donald, A
...
Inorganic Chemistry 3rd Ed (adapted), Pearson, 2009 ISBN 978-8131718858
...
l
...
B
...
Khosla, Practical Chemistry
Teaching Learning Process:
Through chalk and Talk method
...
Correlating the topic with real life cases
...
Through assignment and test
...
Quizzes·
Response of individual student throughout the year and at the end of class
...
Essays
...
Keywords
Metallurgy, Periodicity,Anomalous behaviour , Ellingham diagrams, Hydrometallurgy , Periodicity , Allotropy,
Diagonal relationship, Multicentre bonding , Kinetic Theory, Arrhenius Equation, Bravais Lattice, Miller indices,
Page 42 of 109
Bragg's law, Surface tension, Viscosity, Maxwell Boltzmann Distribution law, Andrews equation
...
DISCIPLINE ELECTIVE COURSES (DSE)
CHEMISTRY (Choose any two)
Applications of Computers in Chemistry
Chemistry DSE 2-4(i)
Total Credits: 06
(Total Lectures: Theory-60)
(Credits: Theory-04, Practicals-02)
Objectives:
The aim of the paper is to make the students of chemistry familiar with the working of computer, programming
language, QBASIC and use of software as a tool to understand chemistry, and solve chemistry based
problems
...
2
...
4
...
Develop algorithm to solve problems and write corresponding programs in BASIC
Write BASIC programs for performing calculations involved in laboratory experiments and research
work
...
Unit 1:
Basic Computer system (in brief)
Hardware and Software; Input devices, Storage devices, Output devices, Central Processing Unit (Control Unit
and Arithmetic Logic Unit); Number system (Binary, Octal and Hexadecimal Operating System);
Computer Codes (BCD and ASCII); Numeric/String constants and variables
...
Debugging Software Products (Office, chemsketch, scilab, matlab, hyperchem, etc
...
(5 Lectures)
Unit 2:
Use of Programming Language for solving problems in Chemistry
Computer Programming Language- QBASIC, (for solving some of the basic and complicated chemistry
problems)
...
Programming Language – QBASIC; arithmetic expressions, hierarchy of operations, inbuilt functions
...
Solution of quadratic equation, polynomial equations (formula, iteration, Newton – Raphson methods, binary
bisection and Regula Falsi); Numerical differential, Numerical integration (Trapezoidal and Simpson’s rule ),
Simultaneous equations, Matrix addition and multiplication, Statistical analysis
...
(40 Lectures)
Unit 3:
Use of Software Products
Computer Software like Scilab, Excel, LibreOffice Calc, etc
...
Handling of experimental data
(15 Lectures)
Practical:
(Credits: 2, Lectures: 60)
Computer programs using QBASIC based on numerical methods
1
...
g
...
Page 44 of 109
2
...
4
...
6
...
Numerical differentiation (e
...
, change in pressure for small change in volume of a van der Waals gas,
potentiometric titrations)
...
g
...
Probability distributions (gas kinetic theory) and mean values
...
Matrix operations: addition, multiplication and transpose
Graphic programs related to Chemistry problems
...
g
...
Use of Software Products
1
...
3
...
Simple exercises using molecular visualization software
...
References:
McQuarrie, D
...
Mathematics for Physical Chemistry University Science Books (2008)
...
Mathematics for Physical Chemistry
...
Elsevier (2005)
...
The Chemical Maths Book Oxford University Press (1996)
...
Chemical Calculations
...
CRC Press (2007)
...
C
...
6th Ed
...
Levie, R
...
Press (2001)
Noggle, J
...
Physical Chemistry on a Microcomputer
...
(1985)
...
M
...
Teaching Learning Process:
Since the course involves programming and use of software, the teaching learning process becomes more
efficient when the theory classes are well coordinated with practical exercises
...
QBASIC is a DOS based language which does not run on 64 bits Windows and Linux based operating
systems
...
Another version which runs on WINDOWS is QB64
...
Assessment Methods:
The students to be assigned projects based on chemistry problems done in class or in practical
classes and use BASIC program to solve it
...
Presentation
Test
Semester end examination
Page 45 of 109
Keywords:
Hardware, software, programming language, ASCII, BCD, QBASIC, Library commands, mathematical
operators, QBASIC commands
Analytical Methods in Chemistry
Chemistry DSE 2-4(ii)
Total Credits: 06
(Total Lectures: Theory-60)
(Credits: Theory-04, Practicals-02)
Objectives:
The objective of this course is to make student aware of the:
1
...
2
...
Thermal and electroanalytical
methods of analysis are also dealt with
...
The practicals expose students to latest instrumentation and
they learn to detect analytes in a mixture
...
2
...
4
...
6
...
8
...
Develop methods of analysis for different samples independently
...
Understand basic principle of instrument like Flame Photometer,UV-VISIBLE
...
Apply knowledge of geometrical isomers and keto-enol tautomers to analysis
...
Estimation of macro nutrients using Flame photometry1
Page 46 of 109
Unit 1:
Qualitative and quantitative aspects of analysis:
Sampling, evaluation of analytical data, errors, accuracy and precision, methods of their expression
...
(5 Lectures)
Unit 2:
Optical methods of analysis
Origin of spectra, interaction of radiation with matter, fundamental laws of spectroscopy and selection rules
...
Absorbance and Lambert-Beer law
...
Flame Atomic Absorption and Emission Spectrometry:
Basic principles of instrumentation (choice of source, monochromator, detector, choice of flame and Burner
designs
...
Techniques for the quantitative estimation of trace level of
metal ions from water samples
...
Techniques for quantitative estimation of
Ca and Mg from their mixture
...
Techniques used for the determination of equivalence points
...
(Lectures:10)
Unit 5:
Separation techniques:
Solvent extraction:
Classification, principle and efficiency of the technique
...
Page 47 of 109
Chromatography:
Classification, principle and efficiency of the technique, Mechanism of separation: adsorption, partition & ion
exchange, Development of chromatograms: frontal, elution and displacement methods
...
by G
...
Jeffery and others) 5 th
Ed
...
Willard, Hobart H
...
: Instrumental Methods of Analysis, 7 th Ed
...
Christian, Gary D; Analytical Chemistry, 6 th Ed
...
Harris, Daniel C: Exploring Chemical Analysis, Ed
...
H
...
Khopkar, S
...
Basic Concepts of Analytical Chemistry
...
Skoog, D
...
, Holler F
...
and Nieman, T
...
Principles of Instrumental Analysis, Thomson Asia Pvt
...
Singapore, 1998
...
and Chalmers, R
...
Ed
...
London
...
V
...
Students are encouraged to participate actively in the classroom through regular presentations on
curriculum based topics
...
Assessment Methods:
Presentations by Individual Student/ Small Group of Students
Class Tests at Periodic Intervals
...
End semester University Theory and Practical Examination
Page 48 of 109
Keywords:
Separation techniques, Solvent extraction,ion-exchange
...
Molecular Modelling and Drug Design
Dr
(Chemistry DSE 2-4(iii)
Total Credits: 06
(Total Lectures: Theory- 60)
(Credits: Theory-04, Practicals-02)
Objectives:
Objective of this course is to make students learn the theoretical background of principles of
computational techniques in molecular modelling, evaluation and applications of different methods for
various molecular systems, energy minimization techniques, analysis of Mulliken Charge& ESP Plots and
elementary idea of drug design
...
Unit 1:
Introduction: Overview of Classical and Quantum Mechanical Methods ( Ab initio, Semi-empirical, Molecuar
Mechanics, Molecular Dynamics and Monte Carlo)
...
Coordinate systems: Cartesian and Internal Coordinates, Bond lengths, bond angles and torsion angles,
Writing Z -matrix (ex: methane, ethane, ethene, ethyne, water, H2O2 ( 5 classes)
(Lectures: 06)
Unit 2:
Potential Energy Surfaces: Intrinsic Reaction Coordinates, Stationary points, Equilibrium points – Local and
Global minima, concept of transition state with examples: Ethane, propane, butane , cyclohexane
...
Page 49 of 109
Applications of computational chemistry to determine reaction mechanisms
...
(Lectures: 12)
Unit 3:
Molecular Mechanics: Force Fields, Non-bonded interactions (van der Waals and electrostatic) , how to
handle torsions of flexible molecules, van der Waals interactions using Lennard-Jones potential, hydrogen
bonding interactions, electrostatic term, Parameterization
...
GUI
...
Intermolecualr Potentials
(Hard sphere, finite square well and Lennar-Jones potentials)
...
Ensembles
(microcanonical, canonical, isothermal – isobaric)
...
Integration of Newton’s equations
(Leapfrog and Verlet Algorithms)
...
Brief introduction to Langevin and Brownian dynamics
...
(Lectures: 10)
Unit 5:
Huckel MO with examples: ethane, propenyl, cyclopropenyl systems, Properties calculated – energy, charges,
dipole moments,bond order, electronic energies, resonance energies, Oxidation and reduction (cationic and
anionic species of above systems)
Extension to Extended Huckel theory and PPP methods
...
Minimal basis sets
...
Koopman’s theorem, Brief idea of Density Functional Theory
...
Other file
formats – PDB
...
QSAR: Structure-activity relationships
...
Biological activities (LD50, IC50, ED50 etc)
...
2
...
4
...
6
...
Plotting a 3D graph depicting a saddle point in a spreadsheet software
...
Determine the heat of hydrogenation of ethylene
...
Is there any relationship between the bond lengths and bond orders? Visualize the highest
occupied and lowest unoccupied molecular orbitals of ethane, ethene, ethyne, benzene and pyridine
...
Compare the basicities of the nitrogen atoms in ammonia, methylamine, dimethylamine and trimethylamine
by comparison of their Mulliken charges and ESP maps
...
Arrange 1-hexene, 2-methyl-2-pentene, (E)-3-methyl-2-pentene, (Z)-3-methyl-2-pentene, and 2,3-dimethyl-2butene in order of increasing stability
...
Compare the optimized bond angles H2O, H2S, H2Se using PM3
...
Compare the HAH bond angles for the second row hydrides (BeH2, CH4, NH3, H2O) and compare with the
results from qualitative MO theory
...
(a) Compare the shapes of the molecules: 1-butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2propanol
...
(b) Show how the shapes affect the trend in boiling points:
(118 ºC, 100 ºC, 108 ºC, 82 ºC, respectively)
...
Compute the resonance energy of benzene by comparison of its enthalpy of hydrogenation with that of
cyclohexene
...
Plot the electrostatic potential mapped on electron density for benzene and use it to predict the type of
stacking in the crystal structure of benzene dimer
...
Predict the aromaticity of thiophene with respect to benzene by comparing the enthalpies of the following
reactions:
(a) Hydrogenation of benzene to 1,3-cyclohexadiene and then 1,3-cyclohexadiene to cyclohexene
...
Docking of Sulfonamide-type D-Glu inhibitor into MurD active site using Arguslab
...
planaria-software
...
Recommended Texts:
References:
Page 51 of 109
Theory:
1
...
3
...
E
...
J
...
R
...
Practicals:
1
...
G
...
, Springer (India) Pvt
...
2011, Ch
...
2
...
& Reid, P
...
, Prentice-Hall 2012, Ch
...
Keywords:
Molecular modelling, Quantum Mechanical Method, Cartesian Coordinates, Molecular Dynamics, Force Field,
Softwares of Computational Chemistry
...
It has found enormous applications in both industrial and research arenas and have helped to
shape modern day recyclable adsorbents and catalysts
...
Materials such as semiconductors, metals, composites, nanomaterials, carbon or high-tech ceramics make life
easier in this era and are great sources of industrial growth and technological changes
...
Course Learning Outcomes:
By the end of the course, the student would be able to:
Page 52 of 109
(i) Understand the mechanism of solid-state synthesis
...
(iii) Understand the concept of nanomaterials, their synthesis and properties
...
(v) Appreciate the existence of bioinorganic nanomaterials
...
(vii) Understand the usage of solid materials in various instruments, batteries, etc
...
Synthesis and modification of inorganic solids: Conventional heat and beat method, Co-precipitation
method, Sol-gel method, Hydrothermal method, Ion-exchange and Intercalation method
...
Inorganic pigments – coloured, white and
black pigments
...
(10 Lectures)
Unit 4:
Nanomaterials: Overview of nanostructures and nanomaterials, classification, preparation and optical
properties of gold and silver metallic nanoparticles, concept of surface plasmon resonance, carbon nanotubes,
inorganic nanowires, Bioinorganic nanomaterials, DNA and its nanomaterials, natural and artificial
nanomaterials, self-assembled nanostructures, control of nanoarchitecture, one dimensional control
...
(10 Lectures)
Unit 6:
Speciality polymers:
Conducting polymers - Introduction, conduction mechanism, polyacetylene, polyparaphenylene, polyaniline
and polypyrole, applications of conducting polymers, ion-exchange resins and their applications
...
(10 Lectures)
Practical:
(Credits: 2, Lectures: 60)
CHEMISTRY PRACTICAL - DSE LAB: NOVEL INORGANIC SOLIDS
1
...
2
...
3
...
4
...
5
...
6
...
7
...
8
...
Page 54 of 109
References:
Theory
·
·
·
·
·
·
·
West, A
...
, Solid State Chemistry and Its Application, Wiley
West, A
...
, Application of Solid State Chemistry, Wiley
Smart, L
...
, Moore, E
...
, Solid State Chemistry An Introduction CRC Press Taylor & Francis
...
N
...
, Gopalakrishnan, J
...
Atkins, Peter, Overton, Tina, Rourke, Jonathan, Weller, Mark and Armstrong, Fraser Shriver & Atkins’
Inorganic Chemistry, 5th Edition, Oxford University Press 2011-2012
Adam, D
...
Inorganic Solids: An introduction to concepts in solid-state structural chemistry, John Wiley
and Sons, London, New York, Sydney, Toronto, 1974
Poole Jr
...
, Owens, Frank J
...
Practical
·
·
·
·
·
·
W
...
M
...
R
...
Chem
...
2015, 92, 339−344
...
MacDiarmid, J
...
Chiang, A
...
Richter, N
...
D
...
L
...
), Conducting Polymers, 105-120,
1987, D
...
Industrial Inorganic Pigments edited by Gunter Buxbaum, Wiley-VCH
K
...
Cheng, A
...
Jacobson, M
...
Whittingham, Hexagonal tungsten trioxide and its intercalation
chemistry, Solid State Ionics, 5, 1981, 355-358
...
R, Mehr F
...
M
...
Orient J Chem 2015;31(2)
...
J
...
E
...
P
...
Educator 2002, 7, 33–36 33
Additional Resources:
https://www
...
com/watch?v=RuyP9kqRcLg
https://www
...
com/watch?v=BGPaywY1wvs
https://www
...
com/watch?v=x5OD2KZXd54
Teaching Learning Process:
Blackboard, Power point presentations, Assignments, Field Trips to Industry, Different working models
ICT enabled classes, Interactive sessions, Debate, recent literature using internet and research articles
Assessment Methods:
Written Examination, Presentations, Quiz
Page 55 of 109
Keywords:
Solid State Chemistry, Nanomaterials, Solid electrolyte, Inorganic Pigments, Self-assembled, Composite
Materials, Instrumentation, Polymers
Research Methodology for Chemistry
Chemistry DSE 2-4 (v)
Total Credits: 06
(Total Lectures: Theory-75, Tutorial-1)
(Credits: Theory-04, Practicals-02)
Objectives:
The objective of this paper is to formulate the research problems and connect the research outcomes to
the society
...
Learning Outcomes:
By the end of the course, the students will be1) Able to identify research problems
...
3) Able to communicate the research at appropriate level
...
Digital: Web resources, E-journals, Journal access, TOC alerts, Hot articles, Citation index, Impact factor, Hindex, E-consortium, UGC infonet, E-books, Internet discussion groups and communities, Blogs, Preprint
servers, Search engines, Scirus, Google Scholar, ChemIndustry, Wiki- Databases, ChemSpider, Science
Direct, SciFinder, Scopus
...
Internet resources for
chemistry
...
Open source Lead lectures
...
(20 Lectures)
Unit 2:
Page 56 of 109
Methods of Scientific Research and Writing Scientific Papers:
Reporting practical and project work
...
Organizing a poster display
...
Writing scientific papers –
justification for scientific contributions, bibliography, description of methods, conclusions, the need for
illustration, style, publications of scientific work
...
Avoiding plagiarism
...
(20 Lectures)
Unit 3:
Chemical Safety and Ethical Handling of Chemicals:
Safe working procedure and protective environment, protective apparel, emergency procedure and first aid,
laboratory ventilation
...
Hazardous Chemicals in Households
...
SI Units and their use
...
Analysis and Presentation of Data: Descriptive statistics
...
Chemometrics
...
Basic aspects of multiple linear regression analysis
...
g
...
Hands on experiments of docking
...
R
...
M
...
, Reed, R
...
& Jones, A
...
Prentice-Hall, Harlow, 2011
...
B
...
J
...
Oxford University Press
...
Topping, J
...
Fourth Ed
...
1984
...
C
...
6th Ed
...
Levie, R
...
Cambridge Univ, 2001
...
OSU safety manual 1
...
Additional Resources:
•
Introductory Biostatistics by Chap T Le
...
It also familiarizes them with coordination compounds
which find manifold applications in diverse fields
...
2
...
With the concepts and methodology of quantum mechanics
...
Basic knowledge of relation between structure determination and spectra
...
2
...
4
...
Properties of d and f block elements
Latimer Diagrams
Properties of coordination compounds
VBT and CFT for bonding in coordination compounds
Basic principles of quantum mechanics : operators, eigen values, averages, probability
distributions
...
Quantisation of translational, rotational and vibrational energies
7
...
Lambert Beer's Law, quantum efficiency and photochemical processes
...
A brief introduction to Latimer diagrams
(Mn, Fe and Cu) and their use to identify oxidizing, reducing species and species which disproportionate
...
Lanthanoids and actinoids: Electronic configurations, oxidation states displayed
...
Lanthanoid contraction(causes and consequences), separation of
lanthanoids by ion exchange method
...
IUPAC system of
nomenclature of coordination compounds (mononuclear and binuclear) involving simple monodentate and
bidentate ligands
...
(6 Lectures)
Page 59 of 109
Unit 3:
Bonding in coordination compounds
Valence Bond Theory (VBT):salient features of theory, Concept of Inner and outer orbital complexes of Cr, Fe,
Co and Ni
...
Crystal field effects for weak and strong fields
...
Factors affecting the magnitude of Δ
...
Splitting of d orbitals in tetrahedral symmetry
...
Jahn-Teller distortion, Square planar coordination
...
2
...
4
...
Free particle
...
Rotational Motion: Schrödinger equation of a rigid rotator and brief discussion of its results (solution
not required)
...
Vibrational Motion: Schrödinger equation of a linear harmonic oscillator and brief discussion of its
results (solution not required)
...
Wave-particle duality
...
Electromagnetic radiation and its interaction with matter
...
Difference between atomic and molecular spectra
...
Microwave (pure rotational) spectra of diatomic molecules
...
Structural information
derived from rotational spectroscopy
...
Structural information derived
from vibrational spectra
...
Group frequencies
...
Electronic Spectroscopy: Electronic excited states
...
Colour and constitution, chromophores, auxochromes, bathochromic
and hypsochromic shifts
...
Lambert-Beer’s law
...
Quantum efficiency and
reasons for high and low quantum yields
...
Photochemical and thermal reactions
...
(6 Lectures)
Practical:
Section A: Inorganic Chemistry
Estimation of the amount of nickel present in a given solution as bis(dimethylglyoximato) nickel(II) or
aluminium as oxinate in a given solution gravimetrically
...
Estimation of total hardness of a given sample of water by complexometric titration
...
Section B: Physical Chemistry
UV/Visible spectroscopy
Study the 200-500 nm absorbance spectra of KMnO4 and K2Cr2O7 (in 0
...
Calculate the energies of the two transitions in different units (J molecule-1, kJ mol-1, cm-1,
eV)
...
Comment on the effect of structure on the UV spectra of organic compounds
...
M
...
J
...
Kotz, P
...
Treichel & J
...
Townsend: General Chemistry, Cengage Lening India Pvt
...
, New
Delhi (2009)
...
H
...
Narosa (1998)
...
D
...
L
...
S
...
A
...
Wilkinson: Basic Inorganic Chemistry, John Wiley
...
Ltd
...
I
...
Page 61 of 109
A
...
Vogel, Quantitative Chemical Analysis, Prentice Hall, 6th Edn
...
D
...
Chand & Co
...
W
...
Narosa (2004)
...
H
...
Macmillan Publishing Co
...
D
...
Shriver and P
...
Atkins: Inorganic Chemistry, Oxford University Press
...
Discussions so that the student can internalize the concepts
...
Assessment Methods:
There should be a multi-pronged approach for evaluating a student’s understanding of the key concepts
...
Organometallics, Bioinorganic Chemistry, Polynuclear Hydrocarbons and
UV, IR Spectroscopy
Total Credits: 06
(Credits: Theory-04, Practicals-02)
(Total Lectures: Theory- 60, Practicals-60)
Page 62 of 109
Objectives:
The purpose of the course is to introduce students of Honours courses other than Chemistry to some important
3d metals and their compounds which they are likely to come across
...
The topics of Polynuclear and Heteronuclear
aromatic hydrocarbons are introduced through some specific examples
...
Learning Outcomes:
On completion of the course, the student will be able to:
Understand the chemistry of the different oxidation states of 3d metals
Get an idea of the preparation and important properties of the familiar compounds potassium
dichromate, potassium permanganate and potassium ferrocyanide
Bonding in organometallic compounds
Use IR data to explain the extent of back bonding in carbonyl complexes
Recognize the role of metal ions present in biological systems with special reference to Na +, K+, Mg2+,
Fe ions
Get a general idea of toxicity of metal ions through the study of Hg2+ and Cd2+ in the physiological
system
The concept of aromaticity and resonance
The preparation, reactions, structure elucidation and toxicity of these aromatic compounds
A new tool for identifying the functional group in organic compounds: Spectroscopy
...
Unit 1:
Chemistry of 3d metals
General discussion of 3d metals
...
A study of the following compounds (including preparation and important properties):
K2Cr2O7, KMnO4, K4[Fe(CN)6]
...
Structure and bonding of methyl lithium and Zeise’s salt
...
18-electron rule as applied to carbonyls
...
pi-acceptor behaviour of carbon monoxide (MO diagram
of CO to be discussed), synergic effect and use of IR data to explain extent of back bonding
...
Role of metal ions present in biological systems with special
reference to Na+, K+ and Mg2+ ions: Na/K pump; Role of Mg2+ ions in energy production and chlorophyll
...
Brief introduction about toxicity
of metal ions (Hg2+and Cd2+)
...
Reactions of naphthalene: reduction, oxidation, electrophilic substitution and Charge transfer complex
formation (picrate)
...
Reactions of anthracene: reduction, oxidation, addition (Diels-Alder reaction), reaction with alkali
metals, electrophilic substitution and charge transfer complex formation (picrate)
...
Special emphasis has to be given to
the following aspects: aromaticity, resonance and toxicity; basicity of pyrrole and pyridine; Hantzch synthesis of
pyrrole and pyridine; reduction, oxidation, addition reactions (Diels-Alder reaction) and electrophilic substitution
reactions; nucleophilic substitution reactions of pyridine
...
Application of Woodward
Rules for calculation of λmax for the following systems: conjugated dienes - alicyclic, homoannular and
heteroannular; α,β-unsaturated aldehydes and ketones, charge transfer complex
...
IR spectra of alkanes, alkenes, aromatic hydrocarbons (effect of
conjugation and resonance on IR absorptions), simple alcohols (inter and intramolecular hydrogen
bonding and IR absorptions), phenol, carbonyl compounds, carboxylic acids and their derivatives
(effect of substitution on >C=O stretching absorptions)
...
Separation of mixtures of two ions by paper chromatography and measurement
of Rf value in each case:
Fe3+, A13+ and Cr3+ or Ni2+, Co2+, Mn2+ and Zn2+
2
...
2
...
4
...
Identification of simple organic compounds containing the above functional groups by IR spectroscopy
through examination of spectra (spectra to be provided)
...
Huheey, Ellen Keiter & Richard Keiter: Inorganic Chemistry: Principles of Structure and
Reactivity, Pearson Publication
G
...
Miessler & Donald A
...
D
...
L
...
S
I
...
Finar: Organic Chemistry (Vol
...
L
...
S
Arun Bahl and B
...
Bahl: Advanced Organic Chemistry, S
...
John R
...
Practical:
V
...
Ahluwalia, Sunita Dhingra and Adarsh Gulati: College Practical Chemistry,
Page 65 of 109
University Press (India) Ltd
...
V
...
Ahluwalia & Sunita Dhingra: Comprehensive Practical Organic Chemistry: Qualitative Analysis,
University Press (2000)
...
I
...
F
...
Mann & B
...
Saunders: Practical Organic Chemistry, Orient Longman (1960)
...
A
...
Wilkinson: Basic Inorganic Chemistry, John Wiley & Sons
...
M
...
C
...
C
...
R
...
Morrison & R
...
Boyd: Organic Chemistry, Prentice Hall
...
Keywords
3d metals; Organometallic Chemistry; Metal Carbonyl; Ferrocene; 18-electron rule; synergic bonding;
Bioinorganic Chemistry; sodium potassium pump; haemoglobin-myoglobin system; polynuclear hydrocarbons;
heteronuclear hydrocarbons; aromaticity; toxicity; UV-visible spectroscopy; IR spectroscopy; charge transfer
spectra
Molecules of Life
Total Credits: 06
(Credits: Theory-04, Practicals-02)
(Total Lectures: Theory- 60, Practicals-60)
Objectives:
1
...
3
...
This includes classification,
reaction chemistry and biological importance of biomolecules
...
Course Learning Outcomes:
1
...
Page 66 of 109
2
...
4
...
The students will gain an insight into mechanism of enzyme action and inhibition
...
The students gain an insight into biological processes like replication ,transcription and translation
...
Unit 1:
Carbohydrates
Classification of carbohydrates, reducing and non reducing sugars, biological functions
...
Epimers, mutarotation and anomers
...
Cyclic structure of glucose
...
Cyclic structure of fructose
...
(10 Lectures)
Unit 2:
Amino Acids, Peptides and Proteins
Classification of amino acids and biological uses of amino Acids, peptides and proteins
...
Determination of primary structure of
peptides, determination of N-terminal amino acid (by DNFB and Edman method) and C– terminal amino acid
(by thiohydantoin and with carboxypeptidase enzyme)
...
Overview of Primary, Secondary, Tertiary and Quaternary structure of proteins
...
(12 Lectures)
Unit 3:
Enzymes and correlation with drug action
Classification of enzymes and their uses(mention Ribozymes)
...
Drug action-receptor theory
...
(10 Lectures)
Unit 4:
Nucleic Acids
Components of Nucleic acids: Adenine, Guanine, Thymine ,Cytosine and Uracil (Structure only), other
Page 67 of 109
components of nucleic acids, nucleosides and nucleotides (nomenclature), Structure of polynucleotides;
Structure of DNA (Watson-Crick model) and RNA(types of RNA),difference between DNA and RNA, Genetic
Code, Biological roles of DNA and RNA: Replication, Transcription and Translation
...
Oils and fats: Common fatty acids present in oils and fats, Omega-3&6
fatty acids, Trans fats, Hydrogenation, Hydrolysis, Acid value, Saponification value, Iodine number
...
(8 Lectures)
Unit 6:
Concept of Energy in Biosystems
Calorific value of food
...
Oxidation of foodstuff
(organic molecules) as a source of energy for cells
...
Conversion of food into
energy
...
Overview
of catabolic pathways of Fats and Proteins
...
(8 Lectures)
Practical:
1
...
3
...
5
...
7
...
test
9
...
Separation of amino acids by paper chromatography
Study of titration curve of glycine and determination of its isoelectric point
...
To determine the saponification value of an oil/fat
...
T
...
N
...
Ltd
...
Finar, I
...
Organic Chemistry (Volume 1), Dorling Kindersley (India) Pvt
...
(Pearson Education)
...
L
...
Ltd
...
Berg, J
...
, Tymoczko, J
...
& Stryer, L
...
, W
...
Freeman
...
S
...
J
...
; Smith, P
...
G
...
R
...
Introduction to Practical Biochemistry by S K Swahney and Randhir Singh,Nerosa Publications
...
Arthur, I
...
Quantitative Organic Analysis, Pearson
...
Certain topics like Mechanism of enzyme action and enzyme inhibition, transcription and translation etc
...
Students are encouraged to participate actively in the classroom through regular presentations on
curriculum based topics
...
Assessment Methods:
Students evaluation done on the basis of regular class test and assignments during the course as per the
curriculum
...
DISSERTATION
DISCIPLINE ELECTIVE COURSES (DSE)
INDUSTRIAL CHEMISTRY
Green Chemistry
Page 69 of 109
Chemistry DSE 2-4(vi)
Total Credits: 06
(Total Lectures: Theory-60)
(Credits: Theory-04, Practicals-02)
Objectives:
Today's society is moving towards becoming more and more environmentally conscious
...
we are faced with a challenge to work towards sustainable practices
...
It is not a new branch of chemistry but the way chemistry should be practiced
...
This is possible because these
undergraduate students are ultimate scientific community of tomorrow
...
2
...
4
...
6
...
Understand stoichiometric calculations and relate them to green chemistry metrics
...
Learn to design safer chemical ,products and processes that are less toxic,than current alternatives
...
Appreciate the use of green chemistry in problem solving skills, critical thinking and valuable skills to
innovate and find out solution to environmental problems
...
Green chemistry is a way to boost profits,increase productivity and ensure sustainability with absolute
zero waste
...
These days customers are demanding to know about a product: Is it green? Does it
contribute to global warming? Was it made from non depletable resources? Students have many
career opportunities as " green" is the path to success
...
Goals of Green Chemistry
...
g
...
Prevention/ minimization of hazardous/ toxic products reducing toxicity
Risk = (function) hazard x exposure ; waste or pollution prevention hierarchy
Designing safer chemicals with minimum toxicity yet has the ability to perform the desired functions
Green solvents: super critical fluids, water as a solvent for organic reactions, ionic liquids, fluorous
biphasic solvent, PEG, solventless processes, solvents obtained from renewable resources and how to
compare greenness of solvents
Energy requirements for reactions – alternative sources of energy: use of microwaves , ultrasonic
energy and photochemical energy
Selection of starting materials; should be renewable rather than depleting
Avoidance of unnecessary derivatization – careful use of blocking/protecting groups
Use of catalytic reagents (wherever possible) in preference to stoichiometric reagents; catalysis and
green chemistry, comparison of heterogeneous and homogeneous catalysis, bio catalysis, asymmetric
catalysis and photo catalysis
...
g
...
Prevention of chemical accidents designing greener processes, inherent safer design, principle of ISD
“What you don’t have cannot harm you”, greener alternative to Bhopal Gas Tragedy (safer route o
carcarbaryl) and Flixiborough accident (safer route to cyclohexanol) subdivision of ISD, minimization,
simplification, substitution, moderation and limitation
...
A new generation of environmentally advanced wood preservatives: Getting the chromium and Arsenic out
of pressure treated wood
...
Healthier Fats and oils by Green Chemistry: Enzymatic Inter esterification for production of No Trans-Fats
and Oils
...
Using a naturally occurring protein to stimulate plant growth, improve crop quality, increase yields, and
suppress disease
...
(10 Lectures)
Practical:
(Credits: 2, Lectures: 60)
CHEMISTRY PRACTICAL - DSE LAB: GREEN CHEMISTRY
Characterization by m
...
, U
...
-Visible spectroscopy, IR spectroscopy, and any other specific method should
be done (wherever applicable)
...
Safer starting materials
Preparation and characterization of nanoparticles of gold using tea leaves/silver nanoparticles using plant
extracts
...
Using renewable resources
Preparation and characterization of biodiesel from vegetable oil preferably waste cooking oil
...
Use of enzymes as catalysts
Benzoin condensation using Thiamine Hydrochloride as a catalyst instead of cyanide
...
Alternative Green solvents
•
•
2
...
Mechanochemical solvent free, solid–solid synthesis of azomethine using p- toluidine and o-vanillin/pvanillin (various other combinations of primary amine and aldehyde can also be tried)
...
Solvent free, microwave assisted one pot synthesis of phthalocyanine complex of copper(II)
...
Reducing waste
Designing and conducting an experiment by utilizing the products and by products obtained in above
preparations which become waste otherwise if not used
...
Some representative examples:
•
•
•
•
•
Use of nanoparticles as catalyst for a reaction
Benzoin converted into Benzil and Benzil into Benzilic acid by a green method
Use of azomethine for complex formation
Rearrangement reaction from Benzopinacol to Benzopinacolone
Conversion of byproduct of biodiesel to a useful product
References:
Theory:
P
...
Anastas & J
...
Warner, Green Chemistry, Theory and Practice, Oxford University Press (1998)
...
Lancaster , Green Chemistry An Introductory Text
...
ISBN: 978-184755-873-2 (2016)
...
C
...
E
...
M
...
Cann and ,Thomas P Umile, Real world cases in Green chemistry vol 11, American chemical
Society,Washington (2008)
A
...
Matlack, Introduction to Green Chemistry, Marcel Dekker (2001)
...
K
...
R
...
L Garay, A
...
L
...
http// Biomimicry
...
Practical:
•
•
•
•
Kirchoff, M
...
A
...
American
Chemical Society, Washington DC (2002)
...
K
...
T
...
K
...
K
...
New Delhi, Bangalore ISBN978-93-81141-55-7 (2013)
...
L
...
H
...
S
...
Indu Tucker Sidhwani et al
...
Manufacturing, applications, analysis and hazards of the Inorganic Chemicals
...
Air and Water pollution, control measures for Air and Water Pollutants
...
Energy and Environment
...
2
...
4
...
6
...
8
...
10
...
12
...
Safe design systems for large scale production of industrial gases
...
Hazardous effects of the Inorganic Chemicals on human beings and vegetation
...
Composition of air, various Air Pollutants, Control measures of Air Pollutants
...
Water treatment and purification methods
...
Different Sources of Energy
...
13
...
Unit 1:
Industrial Gases: Large scale production, uses storage and hazards in handling of the following gases:
oxygen, nitrogen, argon, neon, helium, hydrogen, acetylene, carbon monoxide, chlorine, fluorine, and sulphur
dioxide