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Title: A Level guide for Standard Enthalpy Change
Description: Knowing the different terms for the different enthalpy changes is very important. Especially when the syllabus necessitates candidates to "explain and use the terms". This guide serves to deepen your understanding of each and every term used in energetics for enthalpy. Sample equations are also provided to contextualise the concepts.
Description: Knowing the different terms for the different enthalpy changes is very important. Especially when the syllabus necessitates candidates to "explain and use the terms". This guide serves to deepen your understanding of each and every term used in energetics for enthalpy. Sample equations are also provided to contextualise the concepts.
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Standard Enthalpy Change for A Levels
Sample:
Standard Enthalpy Change of Neutralisation, ∆Hno
It is the energy evolved when one mole of water is formed during neutralisation of an acid and alkali under standard conditions
...
Terms
‘Amt of substance’
used in calculation
Sample Equation
Signs of ∆H
Remarks
∆Hno
Water formed after
neutralisation
NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)
Always –ve
Formation of water
Standard Enthalpy Change of Neutralisation, ∆Hno
It is the energy evolved when one mole of water is formed during neutralisation of an acid and alkali under standard conditions
...
Standard Enthalpy Change of Reaction, ∆Hro
It is the energy change when molar quantities of reactants
as stated in the thermochemical equation react together
under standard conditions
...
First Ionisation Energy, I
...
It is the energy absorbed when one mole of electron is
removed from one mole of gaseous atoms to form one mole
of singly-charged gaseous cations
...
Standard Enthalpy Change of Neutralisation, ∆Hno
It is the energy evolved when one mole of water is formed
during neutralisation of an acid and alkali under standard
conditions
...
First Electron Affinity, E
...
It is the energy changed when one mole of electron is added
to one mole of gaseous atoms to form one mole of singlycharged gaseous anion
...
Standard Enthalpy Change of Combustion, ∆Hco
It is the energy evolved when one mole of a compound is
completely burnt in excess oxygen under standard
conditions
...
Standard Lattice Energy, ∆Hlatto or L
...
It is the energy evolved when one mole of an ionic
compound is formed from its constituent gaseous ions under
standard condition
...
Standard Enthalpy Change of Atomisation, ∆Hatomo
9
...
E
...
Standard Enthalpy Change of Atomisation, ∆Hatomo, of
elements
It is the energy absorbed when one mole of gaseous atoms
is formed from its element under standard conditions
...
5
...
E
...
10
...
11
...
Standard Enthalpy Change for A Levels
S/N
Terms
‘Amt of substance’
used in calculation
Sample Equation
Signs of ∆H
Remarks
1
∆Hro
Overall based on
thermochemical eqn
2H2 (g) + O2 (g) → 2H2O (l)
+/–ve
∆Hr = ∑∆Hf of product –
∑∆Hf of reactant
2
∆Hno
Water formed after
neutralisation
NaOH(aq) + HCl(aq) → NaCl(aq) + H2O(l)
Always –ve
Formation of water
3
∆Hco
Compound before
burning
C3H6 (g) + 4 O2 (g) → 3CO2 (g) + 3H2O (l)
Usually –ve
Energy is usually
released during burning
Gaseous atoms formed
after atomisation
Cl2 (g) → Cl (g)
Always +ve
Breaking the bonds
between atoms
Gaseous compound
before atomisation
C2H6 (g) → 2C (g) + 6H (g)
Always +ve
Breaking bonds in the
compound
4
∆Hatomo
5
∆Hdissoo
Covalent bonds broken
during dissociation
CH4 (g) → CH3 (g) + H (g)
Number of C-H bonds broken
Always +ve
Breaking the bond
between atoms
6
I
...
Electrons removed from
gaseous atoms
Cl (g) → Cl+ (g) + e-
Always +ve
Overcome the attraction
of valence e- and nucleus
7
E
...
Electrons added to
gaseous atoms
O (g) + e- → O- (g)
1st: Always –ve
Usually +ve
e- forms bond with atom;
overcome e- repulsion
8
∆Hlatto
Ionic compound formed
from gaseous ions
Mg2+ (g) + 2Cl- (g) → MgCl2 (s)
Always –ve
Formation of bond
between ions
9
∆Hhydo
Gaseous ions before
hydration
Na+ (g) + aq → Na+ (aq)
Always –ve
Formation of bond
between ion and water
10
∆Hsolo
Substance before
dissolving
MgCl2 (s) + aq → Mg2+ (aq) + 2Cl- (aq)
+/–ve
–ve → soluble
+ve → insoluble
11
∆Hfo
Compound formed from
K (s) + Cl2 (g) + O2 (g) → KClO3 (s)
+/–ve
∆Hfo of element = 0
constituent elements
PS: Unless the definition states that the particles are in its gaseous state, it will always be in its standard state
Title: A Level guide for Standard Enthalpy Change
Description: Knowing the different terms for the different enthalpy changes is very important. Especially when the syllabus necessitates candidates to "explain and use the terms". This guide serves to deepen your understanding of each and every term used in energetics for enthalpy. Sample equations are also provided to contextualise the concepts.
Description: Knowing the different terms for the different enthalpy changes is very important. Especially when the syllabus necessitates candidates to "explain and use the terms". This guide serves to deepen your understanding of each and every term used in energetics for enthalpy. Sample equations are also provided to contextualise the concepts.