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Title: hydrooxy derivates
Description: problems

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1
...
Further compound B undergoes oxidation in the
presence of air to give hydro peroxide C
...
Identify A, B, C and D
...
J–12
(A)
(B)
Benzene
(C)

Cumene
(D)

Cumene hydro peroxide

ANSWER

Phenol

2
...
Compound A on treatment with metallic Na gives compound B
...
This product on acidification gives
compound D (C7H6O3) which is used in medicine
...
O–06
(A)
(B)
Phenol
ANSWER

Sodium phenoxide
(D)

(C)
o-Hydroxy benzoic acid /
Sodium salicylate
Salicylic acid

3
...
B on oxidation gives an acid D
...

Identify the compounds A, B, C and D and explain with proper chemical reactions
...
Compound (A) with molecular formula C6H6O gives violet colour with neutral FeCl3, reacts
with CHCl3 and NaOH and gives two isomers (B) and (C) with molecular formula C7H6O2
...
Compound (D) undergoes carbylamine test
...


(A)

(B)

(C)
p-Hydroxy benzaldehyde

ANSWER

o-Hydroxy benzaldehyde /
Salicylaldehyde
(D)
Aniline / Amino benzene

Phenol

5
...
With CO2 at 400 K/4 to 7
atm
...
Compound A reacts with NH3at
473 K in the presence of anhydrous ZnCl2 to give compound C (C6H7N) which undergoes
carbylamine test
...
O–11 / M–10
(B)
(A)

(C)

o-Hydroxy benzaldehyde /
Salicylaldehyde
(D)

p-Hydroxy benzaldehyde

ANSWER

Aniline / Amino benzene

Phenol

6
...

(A) gives maximum of two isomers (B) and (C) when an alkaline solution of (A) is refluxed with
CCl4
...

Identify (A), (B), (C) and (D)
...
O–07
(B)
(A)
o-Hydroxy benzoic acid /
Phenol
ANSWER
Salicylic acid
(C)
(D)
p-Hydroxy benzoic acid

p-Hydroxy azo benzene

7
...
A gives two isomers
B and C, when an alkaline solution of A is refluxed with CCl4
...
Identify A, B, C and D
...
J-11
(B)
(A)
ANSWER
o-Hydroxy benzoic acid /
Phenol
Salicylic acid

(C)

(D)

p-Hydroxy benzoic acid

p- Hydroxy phenyl methanol

8
...
(A) when heated with
copper at 573 K gives an alkene (C) of molecular formula C4H8
...
Identify (A), (B), (C) and (D) and explain the reactions
...
Compound (A) of molecular formula C3H8O liberates hydrogen with sodium metal
...
Compound (B) on treatment with silver nitrate gives (C) which gives blue colour
with nitrous acid
...
O–09
(A)
(B)
(C)
ANSWER
iso-Propyl alcohol /
2-Iodo propane
2-Nitro propane
2-Propanol
10
...
This on further oxidation forms C (C2H4O2) which gives effervescence with
Na2CO3
...
Identify A, B and C
...
J–07
(A)
(B)
(C)
ANSWER

iso-Propyl alcohol /
2-Propanol

Acetone

Acetic acid

11
...
(B) on further oxidation forms C (C2H4O2) which gives effervescence with
NaHCO3
...
Identify A, B and C
...
J–09
(A)
(B)
(C)
ANSWER
iso-Propyl alcohol /
Acetone
Acetic acid
2-Propanol
12
...
Compound (A) on treatment with sodium hypochlorite gives

a carbonyl compound (B) which on further chlorination gives compound (C) of molecular
formula C3H3OCl3
...
Explain the reactionsM-06
(A)
(B)
(C)
ANSWER
iso-Propyl alcohol /
Acetone
Trichloro acetone
2-Propanol


Title: hydrooxy derivates
Description: problems